Choose the pod -- or female -- flower that will produce the seed pod. Remove the petals. Identify the fringe of yellow pollen-producing structures called stamens that surround the central style. Cut the stamens off with small scissors so they will not accidentally pollinate that flower and so that the pollen will be available for planned pollination of other flowers.
Rose seeds need to go through stratification (an artificial cold spell) for 10 to 12 weeks before they will sprout. This, combined with a germination success rate of 20-30% makes propagation by seed an unattractive prospect. on by seed an unattractive prospect. If you still want to try it, find a good source of information that will guide you through the process.