Soaking the seeds is a crucial step if your seeds will germinate properly and stay clear of any diseases. You MUST not mix the bleach with the hydrogen peroxide as this results in a chemical reaction. 3% peroxide for 24 hours is just fine. This is also a good time to perform the water float test. Remove all seeds that float as they might not be viable.
Allow rose hips to develop by leaving dead flowers on the plant. The flowers are typically pollinated by insects, or pollinate themselves in some varieties, so there is no need to pollinate by hand unless you are breeding specific plants together. Leave the flowers on the rose plant without cutting them. After they wither, small fruits known as rose hips will develop in their place.
The ripened rose hip is then placed on a clean cutting board and cut in half to remove the seeds. Place the seeds in a clean container. Add some diluted bleach to kill off any bacteria and fungus spores. You can make the bleach by mixing drinking water with two teaspoons of household bleach. Stir the seeds well before rinsing them and using bottled water to remove all the bleach. To further clean and disinfect the seeds, put them in the container and add some hydrogen peroxide. The seeds can be soaked for up to 24 hours before rinsing them with clean water to clear all the hydrogen peroxide.
There will be disappointments along the way, when many rose seeds fail to germinate, or perhaps they do germinate, only to die several weeks later from damp-off disease. Sometimes a rose seedling will turn out to be as ugly as sin, or very sickly, and you will reluctantly have to throw it away. Other times they will be just ho-hum, or look too much like its parent, and therefore have no value. But, just when you don't expect it, you might discover that one of your rose seedlings turns out to be very special.