Select the pollen parent flower. Remove the petals and harvest the stamens -- the male flower part that has the pollen -- as in the previous two steps. Check the stamens immediately to see if they are producing fluffy, mature, yellow pollen. If so, proceed to pollination. If not, look at stamens in the vials daily. Use them for pollination when mature pollen is coming loose from the stamens.
If you order bare-root roses from a mail-order company, order early (late winter or early spring). The roses are usually shipped in the spring because bare roots when plants are fully dormant, well before they have leafed out. They’ll look like a bundle of sticks on arrival. Note that they are not dead—simply dormant. Check that the packing material is moist and keep them in a cool dark place until ready to plant.
There will be disappointments along the way, when many rose seeds fail to germinate, or perhaps they do germinate, only to die several weeks later from damp-off disease. Sometimes a rose seedling will turn out to be as ugly as sin, or very sickly, and you will reluctantly have to throw it away. Other times they will be just ho-hum, or look too much like its parent, and therefore have no value. But, just when you don't expect it, you might discover that one of your rose seedlings turns out to be very special.