Select the pollen parent flower. Remove the petals and harvest the stamens -- the male flower part that has the pollen -- as in the previous two steps. Check the stamens immediately to see if they are producing fluffy, mature, yellow pollen. If so, proceed to pollination. If not, look at stamens in the vials daily. Use them for pollination when mature pollen is coming loose from the stamens.
Rose seeds need to go through stratification (an artificial cold spell) for 10 to 12 weeks before they will sprout. This, combined with a germination success rate of 20-30% makes propagation by seed an unattractive prospect. on by seed an unattractive prospect. If you still want to try it, find a good source of information that will guide you through the process.
There will be disappointments along the way, when many rose seeds fail to germinate, or perhaps they do germinate, only to die several weeks later from damp-off disease. Sometimes a rose seedling will turn out to be as ugly as sin, or very sickly, and you will reluctantly have to throw it away. Other times they will be just ho-hum, or look too much like its parent, and therefore have no value. But, just when you don't expect it, you might discover that one of your rose seedlings turns out to be very special.