Select the pollen parent flower. Remove the petals and harvest the stamens -- the male flower part that has the pollen -- as in the previous two steps. Check the stamens immediately to see if they are producing fluffy, mature, yellow pollen. If so, proceed to pollination. If not, look at stamens in the vials daily. Use them for pollination when mature pollen is coming loose from the stamens.
I too, have tried the cut rose flower method, but haven't yet been successful--perhaps because there are chemical additives that the roses have soaked up, or because there are no nodes (which are the points where new shoots grow out), or because the stems have spent much of their energy producing the flowers...BUT, perhaps if the flowers were immediately cut off and some rooting hormones applied to the bottom cut ends, that may work.
If you order bare-root roses from a mail-order company, order early (late winter or early spring). The roses are usually shipped in the spring because bare roots when plants are fully dormant, well before they have leafed out. They’ll look like a bundle of sticks on arrival. Note that they are not dead—simply dormant. Check that the packing material is moist and keep them in a cool dark place until ready to plant.
Fertilizer: Roses are heavy feeders, and will benefit from a steady supply of nitrogen, phosphorus and potassium. You can provide these nutrients with either liquid or granular fertilizers, at a ratio of approximately 5-8-5. In most cases, regular applications of compost, rotted manure, fish emulsion and seaweed extracts will provide roses with all the nutrients they need. These organic amendments also help to moderate pH imbalances and stimulate beneficial soil life. Other organic amendments favored by rose growers include greensand, black rock phosphate and alfalfa meal.