Choose the pod -- or female -- flower that will produce the seed pod. Remove the petals. Identify the fringe of yellow pollen-producing structures called stamens that surround the central style. Cut the stamens off with small scissors so they will not accidentally pollinate that flower and so that the pollen will be available for planned pollination of other flowers.
Growing roses from seed can be challenging, since the majority of seeds you collect often won't germinate regardless of your efforts. Fortunately, most rose plants produce a large quantity of seeds inside their rose hips, so it usually isn't necessary to achieve a high success rate. Keep in mind that the plants that grow may be different in appearance or other characteristics from the mother plant, especially if that plant is a hybrid of two varieties grafted together.
The rose seeds can be planted right away if you have harvested them as late as November, December or January (in Southern California) or early spring after danger of frosts in your area. Place the rose seeds about one-half inch deep in a very light mixture of 50% sterile potting soil and 50% vermiculite. Some rose hybridizers use Sunshine Mix #4. You can use small pots or shallow trays to plant your seeds, whatever works for the space you have, as long as they have good drainage. Nursery flats work well for this. Lightly dust the rose seeds with RooTone or Captan before covering with soil. And then dust the top of the soil again, which will hopefully help to prevent damp-off (a disease which kills young rose seedlings). Amateur rose hybridizers concerned with toxic chemicals may want to periodically spray the seed tray with diluted peroxide and water instead of the more toxic Captan.
Remember that light changes as the angle of the sun shifts throughout the season. If you live in the upper half of the U.S., choose a site that will offer full sun year-round. The more sun you have, the more flowers your plants will produce. In the lower half of the U.S., choose spots with a little bit of afternoon shade. This protects blossoms from the scorching sun and helps your flowers last longer.
Place a jar over each cutting to form a sort of miniature greenhouse for each cutting. It is extremely important that the soil moisture for the cuttings does not dry out at this rooting time. The jar will help to hold humidity in, but can be a problem if it is subjected to a lot of hot afternoon sun, as it will overheat the cutting and kill it, thus the need for shielding against the exposure to the hot afternoon sun when you root roses. Watering of the planting site every other day may be required to keep the soil moist but do not create a standing water or muddy soils situation.