Label the canisters with the name of the pollen parent. Do not put a lid on the canister so they will dry out and not get moldy. After a few hours (on some rose varieties), or the next day (on other varieties), the pollen sacs will burst open, thereby releasing the pollen. Sometimes you will need to shake the canister so that the rose pollen will release from the pollen sacs. The black film canisters make it easy for you to see the pollen, which looks like a fine yellow powder. The pollen will stay fresh for about two weeks.   
When pruning, be judicious. If you prune too hard in autumn, plants can be damaged beyond recovery. Instead, wait until spring, when plants begin to leaf out for the new season. (Roses are often not the earliest plants in the garden to respond to spring’s warming temperatures, so be patient.) Give the plant time to show its leaf buds then prune above that level.
There will be disappointments along the way, when many rose seeds fail to germinate, or perhaps they do germinate, only to die several weeks later from damp-off disease. Sometimes a rose seedling will turn out to be as ugly as sin, or very sickly, and you will reluctantly have to throw it away. Other times they will be just ho-hum, or look too much like its parent, and therefore have no value. But, just when you don't expect it, you might discover that one of your rose seedlings turns out to be very special.   
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